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Aldrich
Chloro(triphenylphosphine)gold(I)
254037 -
≥99.9% trace metals basis
DOWNLOAD MSDS (PDF)Synonym: (Ph3P)AuCl, Triphenylphosphinegold(I) chloride
CAS Number: 14243-64-2
Linear Formula: [(C6H5)3P]AuCl
Molecular Weight: 495.71
EC Number: 238-117-6
MDL number: MFCD00009588
PubChem Substance ID: 24855348
Properties
| Related Categories | Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold, Gold Catalysis, Gold Catalysts |
| assay | ≥99.9% trace metals basis |
Description
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Documents
Certificate of Analysis
| FT-IR Condensed Phase |  |
| FT-IR Raman | |
| ChemFiles Vol 6 No 2 (1 MB ) |
| Structure Search |  |
| Similar Products |
Safety Information
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Fluorinating Reagents
The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinat...
Aldrich ChemFiles 2006, 6.2, 5.
Keywords: Fluorinations, Medicinal chemistry, Metathesis, Organic synthesis, PAGE
Gold Catalysis
Gold catalysis is playing an increasing role in organic synthesis for the facile construction of complex architectures not readily accessed by standard methods. Gold catalysts mediate unique C–C, C–O...
Aldrich ChemFiles 2007, 7.5, 10.
Keywords: Catalysis, Enyne rearrangements, Heterocycle formation, Isomerizations, Organic synthesis, Rearrangements
Intramolecular Hydroamination
An example of the potency of gold catalysis in hydroamination reactions was highlighted in 2006 by Crawley and Funk in the multistep synthesis of communesin B.1 One of the key steps in the synthesis ...
William Sommer
Aldrich ChemFiles 2009, 9.5, 3.
Keywords: Catalysis, Hydroaminations
Related Content
Gold Catalyst in Chemical Synthesis
Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
References
Synlett, 3309, (2006)
J. Org. Chem. 71, 9366, (2006) Abstract
Leseurre, L. et al. Org. Lett. 9, (2007)
Corp MSDS 1 (1), 868:A / FT-IR 2 (3), 4550:A / RegBook 1 (2), 3105:H / Structure Index 1, 492:A:3
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